SUPERPLASTICIZERS FOR MORTARS AND CONCRETES. REVIEW ARTICLE
Abstract
Superplasticizers are chemical additives that improve the flow and workability of concrete and mortar, making them indispensable components of modern construction. This scientific article reviews the latest advances in the development of superplasticizers for mortars and concretes. First, an overview of the chemistry and properties of superplasticizers is presented, including their mechanisms of action and classification based on their chemical composition. It then highlights recent research on the synthesis and effectiveness of new superplasticizers, including those based on polycarboxylate esters, lignosulfonates, and other organic and inorganic compounds. The issues associated with the use of superplasticizers are also discussed, such as their potential impact on concrete durability and environmental sustainability. Our article is a comprehensive resource for researchers and practitioners interested in using superplasticizers to improve the performance of mortars and concretes.
References
P.-C. Aïtcin, M. Baalbaki, Concrete admixtures key components of modern concrete, in A. Aguado, R. Gettu, S.P. Shah (Eds.), Concrete Technology: New Trends, Industrial Applications, E&FN Spon, London, 1994, pp. 33-47.
P.K. Mehta, Advances in concrete technology, Concr. Int. 21 (1999) 69-76.
R.J. Flatt, Towards a prediction of superplasticized concrete rheology, Mater. Struct. 37 (2004) 289-300.
Y. Ma, J. Bai, C. Shi, S. Sha, B. Zhou, Effect of PCEs with different structures on hydration and properties of cementitious materials with low water-to-binder ratio, Cem. Concr. Res. 142 (2021), 106343.
R.J. Flatt, Y.F. Houst, A. simplified view on chemical effects perturbing the action of superplasticizers, Cem. Concr. Res. 31 (2001) 1169-1176.
http://chinaconcretes.com, Retrieved on August 31, 2021.
US Standard Specification for Chemical Admixtures for Concrete. Designation: C494/C494M-17
Shah, S. R., Aslam, M., Shah, S. A., & Oad, R. (2014, july). Behaviour of Normal Concrete Using Superplasticizer under Different Curing Regimes. Pak. J. Engg. & Appl. Sci. Vol. 15, pp. 87-94.
Tamrakar, R., & Mishra, S. Experimental Studies on Property of Concrete due to Different Ingredient based Superplasticizer. International Journal of Science, Engineering and Technology Research,Volume 2, Issue, pp. 1036-1040.
E.V. Tkach. Modifiers in construction technology: Textbook. Karaganda State University. - Karaganda: Publishing house KarGTU, 2006.- 14 p.
Z. A. Kamalova, R. Z. Rakhimov, E. Y. Ermilova, O. V. Stoyanov. Superplasticizers in the production technology of composite concrete. Bulletin of Kazan Technological University. 2013
Ensberger F.M. and France W.G. Some physical and chemical properties of weight-fractionated lignosulphonic acid, including the dissociation of lignosulphonates. Journal of Physic and Colloid Chemistry 52:267-76, 1948
Rixom M.R.. Chemical Admixtures for Concrete, London E&F.N. Spon LTD. 1978
https://promplace.ru/himicheskie-soedineniya-staty/lignosulfonat-2298.htm#menu-1
https://bstudy.net/854620/tehnika/superplastifikatory
Ramachandran V.S. Additives in concrete. Reference Guide. Stroy publishing. 1988. 91-с.
Yakimovich E.T., Levina T.A., Ryzhovsky N.D., Kuten I.I., Rushkevich A.A., Podluzskaya G.I. Complex additive for concrete mixture. Patent RU 2039718 C1. 1995
https://vunivere.ru/work45184/page2
Karpis V.Z. High-performance concretes with additives LST modified with foam suppressants /NIL-21/, for precast concrete: Dissertation ... Candidate of Technical Sciences. / М., 1989. 22с
Concretes. Materials. Technologies. Equipment. M.: Stroyinform, Rostov n / d: Phoenix, 2006. -424 f.: ill.
Plasticizing additives for concrete. Specialized industrial and practical guidebook. Edited by V. Lozhkin. P. 2013.
Kastornykh L.I. Additives in concrete and mortars. Educational and reference manual. 2 ed. 2007-y. 12-page.
PLANK, J., Verleihung der Hans-Kühl-Medaille 2003, GDCh-Monographie 27, Hrsg
Alois Aignesberger, SURFACTANT COMPOSITION. United States Patent Office, 1972
[https://pandia.ru/text/80/371/51558-3.php
Trinker A.B. Lignosulfonates and electrolytes in concrete. History of creation and application. Surfactants and ersavers. https://ardexpert.ru/article/12864
Tkach E.V., Imanov M.O., Rakhimov M.A. Application of hydrophobic modifiers for obtaining hydrophobic cements of low water consumption // Bulletin of the Kazakh Academy of Transport and Communications. - Almaty.- 2005. -№3 (34). - С. 7-12.
Kh. Kamilov , A. Zaitov, A. Tulaganov. On a formula finding fractal dimension. Archives of Materials Science and Engineering. Volume 104, Issue 1, p.19-22, 2020. DOI:10.5604/01.3001.0014.3865
Recommendations for physical and chemical control of composition and quality of superplasticizer C-3. NIIZHB GOSSTROY OF THE USSR. Moscow 1984
M.N. Dolgacheva, M.G. Osmolovskaya. Study of application and dosage of plasticizing additives in concrete mixtures taking into account mineralogical and material composition of cement. "Bulletin of the Belarusian State University of Transport: Science and Transport". 2013. № 2 (27)
V.S. Izotov, Yu.A. Sokolova. Chemical additives for concrete modification. Moscow: Kazan State University of Architecture and Civil Engineering: Publishing house "Paleotype", 2006. - 244 с.
https://studref.com/546733/stroitelstvo/kratkaya_harakteristika_dobavok
A.P. Shvedov, S.F. Yakubovsky. Production of chemical additives in concrete based on sulfurization of inorganic products. INDUSTRY. APPLIED SCIENCES. Chemical Technology. №11 2011 г.
https://bstudy.net/815827/tehnika/plastifitsiruyusche_vodoredutsiruyuschie_dobavki
http://stroy-server.ru/notes/vidy-plastifitsiruyushchikh-dobavok
https://www.cormix.com/product-hilight/
Lomar® D Powder Product Bulliten. Website: www.geosc.com
Modern superplasticizers and thinners for concrete. Edited by Lozhkin V.P. Specialized industrial and practical handbook. Kaliningrad, 2013.
P.S. Krasovsky. Physico-chemical bases of cement structure formation Concretes: textbook / P.S. Krasovsky. - Khabarovsk: Publishing house Far Eastern State University of Railway Transport, 2013 - 204 p.
Yargin I.N., Yavorsky A.A. Modern chemical additives in the technology of monolithic concrete. INTERUNIVERSITY COLLECTION OF ARTICLES. Nizhny Novgorod State University of Architecture and Civil Engineering. 2009 г. 272-page.
Sikament FF - Technical Data Sheet.
T. Hirata, Working Mechanism and Material Design of Polycarboxylate-ether (PCE) Superplasticizers for Concrete, Hokkaido University, 2010. Ph.D. thesis.
T. Hirata, Cement dispersants, JP patent, 842022 (S59-018338), 1981.
R.J. Flatt, Dispersion forces in cement suspensions, Cem. Concr. Res. 34 (2004) 399-408
K. Hattori, Development of superplasticizers, Concr. J. 40 (2002) 27-35.
K. Yoshioka, E. Sakai, M. Daimon, A. Kitahara, Role of steric hindrance in the performance of superplasticizers for concrete, J. Am. Ceram. Soc. 80 (1997) 2667-2671.
J.A. Lewis, H. Matsuyama, G. Kirby, S. Morissette, J.F. Young, Polyelectrolyte effects on the rheological properties of concentrated cement suspensions, J. Am. Ceram. Soc. 83 (2000) 1905-1913.
P.F.G. Banfill, A discussion of the papers "rheological properties of cement mixes" by M. Daimon and D. M. Roy, Cem. Concr. Res. 9 (1979) 795-796.
G. Gelardi, R.J. Flatt, Working mechanisms of water reducers and superplasticizers, in: P.-C. Aïtcin, R.J. Flatt (Eds.), Science and Technology of Concrete Admixtures, Elsevier, 2016, pp. 257-278.
R.J. Flatt, P. Bowen, Electrostatic repulsion between particles in cement suspensions: Domain of validity of linearized Poisson-Boltzmann equation for nonideal electrolytes, Cem. Concr. Res. 33 (2003) 781-791
Lei Lei, Tsuyoshi Hirata, Johann Plank. 40 years of PCE superplasticizers - History, current state-of-the-art and an outlook. Cement and Concrete Research. 2022
Z. A. Kamalova, R. Z. Rakhimov, E. Y. Ermilova, O. V. Stoyanov. Superplasticizers in the production technology of composite concrete. Bulletin of Kazan Technological University. 2013
Lei Lei. A Comprehensive Study of Interactions Occurring Between Superplasticizers and Clays, and Superplasticizers and Cement. Dissertation. Lehrstuhl für Bauchemie, Technische Universität München, München 2016
J. Guicquero, P. Maitrasse, M. Mosquet, A. Sers, A water soluble or water dispersible dispersing agent, FR patent, 2776285, 1999.
J. Plank, K. Pöllmann, N. Zouaoui, P. R. Andres, C. Schaefer, Synthesis and performance of methacrylic ester based polycarboxylate superplasticizers possessing hydroxy terminated poly (ethylene glycol) side chains, Cem. Concr. Res. 38 (2008) 1210-1216.
S.A. Weckwerth, W. Radke, R.J. Flatt, A method for characterizing the chemical heterogeneity of comb-copolymers and its dependence on synthesis routes, Polymers. 13 (2021) 1921.
A. Lange, T. Hirata, J. Plank, Influence of the HLB value of polycarboxylate superplasticizers on the flow behavior of mortar and concrete, Cem. Concr. Res. 60 (2014) 45-50.
S.-I. Akimoto, S. Honda, T. Yasukohchi, Additives for Cement, EP 0291073, 1987.
Lange, A., Studien zur Zementkompatibilität von Polycarboxylat-Fließmitteln sowie zum Einfluss ihres HLB-Wertes auf das rheologische Verhalten von Mörtel. Dissertation, Lehrstuhl für Bauchemie, Technische Universität München, München 2015
Markus Philipp Schönlein. Investigations on the very first nucleation and growth of early cement hydrate phases. Dissertation Lehrstuhl für Bauchemie.
G. Albrecht, J. Weichmann, J. Penkner, A. Kern, Copolymers based on oxyalkyleneglycol alkenyl ethers and derivatives of unsaturated dicarboxylic acids, EP 0736553 B1, 1996
D. Hamada, F. Yamato, T. Mizunuma, and H. Ichikawa. Additive mixture for cement-based concrete or mortar contains a copolymer of polyalkoxylated unsaturated acid and a mixture of alkoxylated carboxylic acid with a corresponding ester and/or an alkoxylated alcohol. DE 10048139, 2001.
Z. Wang, Y. Xu, H. Wu, X. Liu, F. Zheng, H. Li, S. Cui, M. Lan, and Y. Wang. A room temperature synthesis method for polycarboxylate superplasticizer, CN 103897119, 2013
M. Yamamoto, T. Uno, Y. Onda, H. Tanaka, A. Yamashita, T. Hirata, and N. Hirano. Copolymer for cement admixtures and its production process and use, US Patent, 6,727,315, 2004.
T. Amaya, A. Ikeda, J. Imamura, A. Kobayashi, K. Saito, W. Danzinger, and T. Tomoyose. Cement dispersant and concrete composition containing the dispersant, US 7393886, 2000
S. Ng, J. Plank, Interaction mechanisms between Na montmorillonite clay and MPEG-based polycarboxylate superplasticizers, Cem. Concr. Res., 42, 2012, 847-854.
M. Nehdi, Clay in cement-based materials: critical overview of state-of-the-art, Constr. Build. Mater., 51, 2014, 372-382
L. Bailey, M. Keall, A. Audibert, J. Lecourtier, Effect of clay/polymer interactions on shale stabilization during drilling, Langmuir, 10, 1994, 1544-1549.